Document Details

Document Type : Article In Journal 
Document Title :
Modern Friedel-Crafts chemistry. Part 26. A facile synthesis of trans-2-methyl-1-phenylindan via rearrangement-intramolecular cyclo-alkylation of 1,3-diphenyl-2-methyl-2-propanol under Friedel-Crafts conditions
كيمياء فريدل – كرافتس الحديثة - الجزء 26. من السهل تشييد trans-2-methyl-1-phenylindan من خلال إعادة ترتيب تحلق الأكلة الداخلية لـ 1,3-diphenyl-2-methyl-2-propanol تحت ظروف فريدل - كرافتس
 
Subject : Organic Chemistry 
Document Language : English 
Abstract : 1,2-Diphenyl-2-methyl-2-propanol (1) was prepared by two alternative Grignard methods. Treatment of 1 with AlCl3, AlCl3/CH 3NO2 or K10 clay catalyst in benzene, toluene of dichloromethane solvent at varying temperatures for varying times gave trans-2-methyl-1-phenylindan (4) as sole or major product. Side products including isomeric alkenes 7 and 8, isomeric chlorides 9 and 10, isomeric triarylated isobutanes 11-14, 1-methyl-3-phenylindan (5) and 2-methyl-1-phenylindene (6) were also detected by GC-MS technique. Mechanistic interpretations and explanatory comments are offered. 
ISSN : 0019-4522 
Journal Name : Journal of the Indian Chemical Society 
Volume : 81 
Issue Number : 6 
Publishing Year : 1425 AH
2004 AD 
Article Type : Article 
Added Date : Saturday, June 21, 2008 

Researchers

Researcher Name (Arabic)Researcher Name (English)Researcher TypeDr GradeEmail
على على خلفKhalaf, Ali AliInvestigatorDoctoratehalbar@kau.edu.sa
حسن عبدالقادر البارAlbar, Hassan AbdulkaderResearcherDoctoratehalbar@kau.edu.sa

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